Amber Valletta as Catherine Deneuve wearing Belle de Jour Lipstick

Supermodel Amber Valletta has walked hundreds of runways, appeared on countless covers, and has been the face of Louis Vuitton, Calvin Klein and Versace. She has also appeared in many films such as What Lies Beneath, The Family Man, and Hitch, and works internationally to raise awareness about the dangers of mercury in our waters. She appears as legendary French model and actress Catherine Deneuve in her most iconic role as a housewife turned prostitute in 1967’s Belle de Jour. She wears Belle de Jour Lipstick, a demure sheer beige. “I really wanted to use Belle de Jour—it’s one of my favorite shades and perfect for this fun, young interpretation of Catherine Deneuve,” says François. Proceeds to benefit The Friendly House.

Daphne Guinness in Modern Edwardian wearing Night Breed Single Eyeshadow

Daphne Guinness is a style icon, socialite, heiress, film producer and fashion designer, and a regular fixture in the most exclusive front rows. She has a legendary haute couture collection, impeccable taste, and never disappoints fashion critics. She appears in modern, glittering metallic Edwardian clothing, hat, and a mixture of Erickson Beamon and her own jewelry. “This look is so Daphne—very sultry, very sexy, very evening—so daring. Daphne can pull anything off—she’s such an inspiration,” says François. She wears the Night Breed Single Eyeshadow, a black with silver glitter hue that can be worn sheer or layered as it is here—perfect for creating a little drama. Proceeds to benefit Meath Women’s Refuge & Support Services.

Marc Jacobs as China Machado wearing Dovima Nail Polish

American fashion designer Marc Jacobs knows a thing or two about icons. He is as famous for his unusual and ingenious choice of models and collaborative partnerships as he is for his stirring designs—at both his eponymous fashion house and at Louis Vuitton, where he serves as Creative Director. He appears as 1960s supermodel China Machado in a photograph taken by legendary photographer Richard Avedon, who has always been an inspiration to François. “China is wearing bright red polish in her 1959 photo, so I wanted Marc to do the same—plus he’s always up for anything,” says François. Marc wears Dovima Nail Polish, named for one of Avedon’s favoritemodels—a very modern, very sophisticated bold tomato red. Proceeds to benefit amfar.

Naomi Campbell as an Iconic Supermodel wearing Taj Mahal Blush

Naomi Campbell was an overnight sensation when she began her career in the mid-eighties, changing the face of the industry as the first black model to appear on the covers of French, British, and Japanese Vogue. She was famously filmed for George Michael’s Freedom ’90 video, as well as for Madonna’s Erotica video, and has appeared on over 100 magazine covers. She is a supermodel in the truest sense. Naomi is the epitome of glamour in an Olivier Theyskens for Nina Ricci dress, and Taj Mahal Blush, a burnt orange with shimmer. “Naomi is one of the most iconic symbols of beauty today, and I wanted to use a makeup color that would show this by name and by hue. It’s a bright shade, but sheer, so it looks very natural and yet, ultra-glam—just like her,” says François. Proceeds to benefit White Ribbon Alliance.